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Journal of the Geological Society; 2009; v. 166; issue.1; p. 183-191;
DOI: 10.1144/0016-76492007-171
© 2009 Geological Society of London

Research Article

Constraints on 87Sr/86Sr of Late Ediacaran seawater: insight from Siberian high-Sr limestones

V.A. Melezhik1,2, B.G. Pokrovsky3, A.E. Fallick4, A.B. Kuznetsov5 & M.I. Bujakaite3

1 Geological Survey of Norway, Leiv Eirikssons vei 39, N-4791, Trondheim, Norway
2 Centre for Geobiology, University of Bergen, PO Box 7803, N-5020 Bergen, Norway
3 Geological Institute, Russian Academy of Sciences, Pyzhevsky 7, 119017 Moscow, Russia
4 Scottish Universities Environmental Research Centre, East Kilbride, Glasgow G75 0QF, UK
5 Institute of Precambrian Geology and Geochronology, nab. Makarova, 2, 199034 St. Petersburg, Russia

*Corresponding author (e-mail: victor.melezhik{at}ngu.no)

In SE Siberia, carbonate formations with {delta}13Ccarb values ranging between –12{per thousand} and –7{per thousand} (V-PDB) and Sr concentrations of up to 2.5% occupy an area of 40 000 km2. Several successions exceed 1000 m in thickness and represent the world's largest known exposures of sedimentary carbonates exhibiting extreme depletion in 13C. The carbonates were deposited on a carbonate platform evolving from a mixed carbonate–siliciclastic ramp to a carbonate ramp, and then from a peritidal rimmed shelf to a deep-water open shelf. All sequences reveal a facies-independent, upward rise in marine {delta}13Ccarb from –12{per thousand} to –7{per thousand}. The trend and magnitude of the values mimic those that are characteristic of the 600–550 Ma Shuram–Wonoka isotope event. A coincident stratigraphic rise in 87Sr/86Sr from 0.70802 to 0.70862 in several sections of limestones, containing 4400 µg g–1 Sr on average, is considered to be by far the best available constraint on a temporal variation of seawater isotopic composition through the Late Ediacaran. If the greatest temporal rate of change in seawater 87Sr/86Sr observed in the Cenozoic is applied to the Siberian sections, the calculated minimum duration for the Suram–Wonoka event is 10 Ma.

Supplementary material: XRF and ICP-AES analysis, C, O and Sr isotopic data are available at http://www.geolsoc.org.uk/SUP18324.